
About
Biography
I started my academic career as a physicist by training. I went to Wuhan University in October 1978 to read a four year BSc degree course in Semiconductor Physics. This was followed by a three year MSc degree course in Solid State Physics from September 1982 to August 1985.
From September 1985, I became a junior staff member working in Physics Department at Wuhan University, first as demonstrator and then promoted to junior lecturer position two years later. My research interest at Wuhan University was on the electronic structures and optical properties of layered 3d transition metal intercalated transition metal dichalcogenide crystals.
In 1988, I was awarded a Bank of Credit and Commerce International (BCCI) scholarship and Overseas Research Scholarship (ORS) for my PhD study in Physics and Chemistry of Solids (PCS) Group at Cavendish Laboratory, Cambridge University.
My PhD thesis was on isomorphic site selective substitution in high temperature superconducting YBa2Cu3O7-δ. I moved to School of Chemistry at Leeds University in January 1992 to work on high pressure and high temperature solid state synthesis of novel perovskite oxides such as CaFeO3-δ, then to School of Chemistry at St Andrews in March 1995 to work on SrNbO3-δ.
I joined Surrey Ion Beam Centre from January 1998, first on the fabrication of high temperature superconductor Josephson junctions using masked ion beam irradiation, later as a Liaison Fellow working with a number of research projects supported by EPSRC and other funding agencies.
ResearchResearch interests
In a few words, my research interest is mainly on the experimental manipulation of physical properties of novel solid state materials under extreme physical conditions such as temperature, pressure and ion beam irradiation/implantation etc. Typical examples include:
- Introduction of point defects in establishing magnetic ordering in conventional semiconducting materials, in suppressing superconductivity and in studying robust structural materials
- Manipulation oxygen nonstoichiometry in perovskite oxides on magnetic ordering and lattice distortion
- Ion beam synthesis of novel materials.
Research interests
In a few words, my research interest is mainly on the experimental manipulation of physical properties of novel solid state materials under extreme physical conditions such as temperature, pressure and ion beam irradiation/implantation etc. Typical examples include:
- Introduction of point defects in establishing magnetic ordering in conventional semiconducting materials, in suppressing superconductivity and in studying robust structural materials
- Manipulation oxygen nonstoichiometry in perovskite oxides on magnetic ordering and lattice distortion
- Ion beam synthesis of novel materials.
Publications
An understanding of the effect of cumulative radiation damage on the integrity of ceramic wasteforms for plutonium and minor actinide disposition is key to the scientific case for safe disposal. Alpha recoil due to the decay of actinide species leads to the amorphisation of the initially crystalline host matrix, with potentially deleterious consequences such as macroscopic volume swelling and reduced resistance to aqueous dissolution. For the purpose of laboratory studies the effect of radiation damage can be simulated by various accelerated methodologies. The incorporation of short-lived actinide isotopes accurately reproduces damage arising from both alpha-particle and the heavy recoil nucleus, but requires access to specialist facilities. In contrast, fast ion implantation of inactive model ceramics effectively simulates the heavy recoil nucleus, leading to amorphisation of the host crystal lattice over very short time-scales. Although the resulting materials are easily handled, quantitative analysis of the resulting damaged surface layer has proved challenging. In this investigation, we have developed an experimental methodology for characterisation of radiation damaged structures in candidate ceramics for actinide disposition. Our approach involves implantation of bulk ceramic samples with 2 MeV Kr+ ions, to simulate heavy atom recoil; combined with grazing incidence X-ray absorption spectroscopy (GI-XAS) to characterise only the damaged surface layer. Here we present experimental GI-XAS data acquired at the Ti and Zr K-edges of ion implanted zirconolite, as a function of grazing angle, demonstrating that this technique can be successfully applied to characterise only the amorphised surface layer. Comparison of our findings with data from metamict natural analogues provide evidence that heavy ion implantation reproduces the amorphous structure arising from naturally accumulated radiation damage.
Progress in ion implantation of metal ions into substrates of amorphous silica or Si-nitride with respect to lateral periodic patterning is presented. We use a 2D-nanoporous membrane of anodic aluminium oxide (AAO) as mask to conduct the Co ion implantations. The criteria for successful masked implantation and main problems are presented, including testing of the masks in a focused ion beam (FIB) system. It is proposed that electron transparent thin windows are the most suitable substrate for methods development, as TEM observation can be followed without any further sample milling. Co clusters are found to exhibit the same lateral order as the pores, and first annealing tests to achieve Co nanoparticles are shown using an in-situ heating TEM holder. © 2012 IEEE.
Penetration of a nanochannel mask by 190keV Co ions is tested for the purpose of achieving laterally modulated ion implantation into a SiO thin film on a Si substrate. A 2D-nanoporous membrane of anodic aluminum oxide (AAO) is chosen as the mask. Criteria and challenges for designing the mask are presented. Implantation experiments through a mask with pore diameter of 125 nm and inter-pore distance of 260 nm are carried out. Cross-sectional TEM (XTEM) is shown as an ideal tool to assess depth distribution and lateral distribution of implanted ions at the same time, complemented by Rutherford backscattering spectroscopy. Using energy dispersive x-ray spectroscopy linescans, a Co distribution with lateral modulation is found at 120 nm below the oxide surface. First experiments in converting the atomic distribution of Co to discrete nanoparticles by in-situ TEM annealing are presented. © 2012 Materials Research Society.
We have studied the magnetization of vertically aligned graphene nanoflakes irradiated with nitrogen ions of 100 KeV energy and doses in the range 10¹¹–10¹⁷ ions/cm². The non-irradiated graphene nanoflakes show a paramagnetic contribution, which is increased progressively by ion irradiation at low doses up to 10¹⁵/cm². However, further increase on implantation dose reduces the magnetic moment which coincides with the onset of amorphization as verified by both Raman and x-ray photoelectron spectroscopic data. Overall, our results demonstrate the absence of ferromagnetism on either implanted or unimplanted samples from room temperature down to a temperature of 5 K.
The electrical characteristics of gallium-doped zinc oxide (ZnO:Ga) thin films prepared by rf diode sputtering were altered via nitrogen implantation by performing two implants at 40 keV and 80 keV with doses of 1×1015 and 1×1016 cm−2 to achieve a p-type semiconductor. An implantation of 1×1015 cm−2 N+-ions yielded a p-type with hole concentrations 1017–1018 cm−3 in some as-implanted samples. The films annealed at temperatures above 200°C in O2 and above 400°C in N2 were n-type with electron concentrations 1017–1020 cm−3. The higher nitrogen concentration (confirmed by SRIM and SIMS), in the films implanted with a 1×1016 cm−2 dose, resulted in lower electron concentrations, respectively, higher resistivity, due to compensation of donors by nitrogen acceptors. The electron concentrations ratio n(1×1015)/n(1×1016) decreases with increasing annealing temperature. Hall measurements showed that 1×1016 cm−2 N-implanted films became p-type after low temperature annealing in O2 at 200°C and in N2 at 400°C with hole concentrations of 3.2×1017 cm−3 and 1.6×1019 cm−3, respectively. Nitrogen-implanted ZnO:Ga films showed a c-axes preferred orientation of the crystallites. Annealing is shown to increase the average transmittance (>80%) of the films and to cause bandgap widening (3.19–3.3 eV).
An apparatus has been built to perform irradiation and electrical testing of REBCO coated conductors (CC) held below their critical temperature (Tc). Patterned tracks of Fujikura GdBCO CC were irradiated with 2 MeV He+ ions in steps up to 4 mdpa whilst held at 40 K, and the critical current density (Jc) determined from I–V characteristics. These 'in-situ' samples then underwent annealing experiments at room temperature. The superconducting performance, both before and after room temperature annealing, has been compared to equivalent samples irradiated at room temperature and then cooled for testing at 40 K to understand how the damage tolerance of these materials is affected by sample temperature. Details of the apparatus and experimental results from preliminary work are presented and discussed. These preliminary results show that both Tc and Jc values of patterned tracks degrade with irradiation dose, with most samples showing similar behaviour. The room temperature annealing of 'in-situ' irradiated samples resulted in a significant recovery of properties. We conclude that irradiation temperature does alter how the superconducting properties of GdBCO CC are affected by ion irradiation, and that this observation has implications for the design of high temperature superconducting magnets for future fusion reactors.
Transparent conductors are a vital component of smartphones, touch-enabled displays, low emissivity windows and thin film photovoltaics. Tin-doped In2O3 (ITO) dominates the transparent conductive films market, accounting for the majority of the current multi-billion dollar annual global sales. Due to the high cost of indium, however, alternatives to ITO have been sought but have inferior properties. Here we demonstrate that molybdenum-doped In2O3 (IMO) has higher mobility and therefore higher conductivity than ITO with the same carrier density. This also results in IMO having increased infrared transparency compared to ITO of the same conductivity. These properties enable current performance to be achieved using thinner films, reducing the amount of indium required and raw material costs by half. The enhanced doping behavior arises from Mo 4d donor states being resonant high in the conduction band and negligibly perturbing the host conduction band minimum, in contrast to the adverse perturbation caused by Sn 5s dopant states. This new understanding will enable better and cheaper TCOs based on both In2O3 and other metal oxides.
Transmission electron microscopy (TEM) of ex-situ He ion irradiated bulk W has been performed to quantitatively compare the damage microstructure to that observed in regions of comparable thicknesses during in-situ ion irradiation with TEM experiments. Samples were irradiated to achieve He-appm/DPA ratios of 2000 and 500 at temperatures of 500 and 800 °C to 1.5 and 3.0 DPA. For irradiations at 500 °C, bubble diameters (∼2 nm) were larger and areal bubble densities (∼1012 bubbles/cm2) were lower than those in the in-situ experiments. This is attributed to greater amounts of He being retained in the ex-situ bulk experiments whereas in the in-situ experiments some may escape due to the proximity of surfaces. Dislocation loops were observed in all samples and were characterised as b = ±½ type with no b = type loops. Dislocation loop populations were dominated by interstitial type (∼60%) agreeing with in-situ experiments. However, dislocation loops in this work were larger, ranging in size from 7 to 100 nm and large concentrations of entangled dislocation lines were observed in the bulk of the grain as compared to in the in-situ experiments.
The nature of the electronic state of a metal depends strongly on its dimensionality. In a system of isolated conducting chains, the Fermi-liquid (quasiparticle) description appropriate for higher dimensions is replaced by the so-called Tomonaga-Luttinger liquid picture characterized by collective excitations of spin and charge. Temperature is often regarded as a viable tuning parameter between states of different dimensionality, but what happens once thermal broadening becomes comparable to the interchain hopping energy remains an unresolved issue, one that is central to many organic and inorganic conductors. Here we use the ratio of the thermal to electrical conductivities to probe the nature of the electronic state in PrBa2Cu4O8 as a function of temperature. We find that despite the interchain transport becoming non-metallic, the charge carriers within the CuO chains appear to retain their quasiparticle nature. This implies that temperature alone cannot induce a crossover from Fermi-liquid to Tomonaga-Luttinger-liquid behaviour in quasi-one-dimensional metals.
The effect of 600 keV He+ ion irradiation on the temperature and magnetic field dependence of the critical current density JC in high quality BaFe1.84Co0.16As2 (Co-doped Ba122 type) thin films is investigated. The films are prepared by pulsed-laser-deposition (PLD) on CaF2 (00 $l$) substrates. The irradiation dosages are varied between 1 × 1013 and 1 × 1016 cm−2. Upon irradiation, the superconducting transition temperature TC drops slightly from 25 K for the unirradiated sample to about 20 K for the sample with the highest irradiation level. The JC values of the thin film samples are calculated by using the Bean critical state model. The results showed that JC could be enhanced substantially. The maximum JC value at 4.5 K temperature is enhanced up to 2.4 MA cm−2 under 1 T field. The analysis of pinning force dependence on magnetic field shows that the pinning behavior is not changed in the irradiated samples, suggesting more pinning centers of similar nature to those of presented in the unirradiated samples are introduced by the irradiation process. The results indicate that the irradiation of light element ions He+ with relatively low energy could increase the critical current density in iron based superconductors.
The polarization beam splitter is a key component for polarization manipulation in photonic integrated circuits, but it is challenging to design for low-refractive-index optical materials, due to the low birefringence of the waveguides. We propose what we believe is a novel compact vertical-dual-slot waveguide-based coupling scheme for silicon carbide, enabling efficient low-birefringence polarization splitting by extensively modulating the transverse-magnetic mode distribution. We numerically and experimentally demonstrate the device in the 4H-silicon-carbide-on-insulator integrated platform, with a small footprint of 2.2 μm×15 μm. The device, easy to fabricate via a single lithography process as other components on the chip, exhibits low insertion loss of
Materials research for advances in fusion technologies will depend an analytical sensitivity to Li, but appropriate nuclear reaction cross-sections are very poorly known. Here we determined the differential cross-sections for 7Li(3He,p0~4)9Be, 7Li(3He,d0)8Be and 6Li(3He,p0)8Be from 1.2 to 3 MeV at a lab angle of 146°. All sources to the total combined standard uncertainty in the measurement were discussed in detail.
Understanding the effect of radiation damage and noble gas accommodation in potential ceramic hosts for plutonium disposition is necessary to evaluate their long-term behaviour during geological disposal. Polycrystalline samples of Nd-doped zirconolite and Nd-doped perovskite were irradiated ex situ with 2 MeV Kr+ at a dose of 5 1015 ions cm2 to simulate recoil of Pu nuclei during alpha decay. The feasibility of thin section preparation of both pristine and irradiated samples by Focused Ion Beam sectioning was demonstrated. After irradiation, the Nd-doped zirconolite revealed a well defined amorphous region separated from the pristine material by a thin (40–60 nm) damaged interface. The zirconolite lattice was lost in the damaged interface, but the fluorite sublattice was retained. The Nd-doped perovskite contained a defined irradiated layer composed of an amorphous region surrounded by damaged but still crystalline layers. The structural evolution of the damaged regions is consistent with a change from orthorhombic to cubic symmetry. In addition in Nd-doped perovskite, the amorphisation dose depended on crystallographic orientation and possibly sample configuration (thin section or bulk). Electron Energy Loss Spectroscopy revealed Ti remained in the 4+ oxidation state but there was a change in Ti coordination in both Nd-doped perovskite and Nd-doped zirconolite associated with the crystalline to amorphous transition.
Lateral ordered Co, Pt and Co/Pt nanostructures were fabricated in SiO2 and Si3N4 substrates by high fluence metal ion implantation through periodic nanochannel membrane masks based on anodic aluminium oxides (AAO). The quality of nanopatterning transfer defined by various AAO masks in different substrates was examined by transmission electron microscopy (TEM) in both imaging and spectroscopy modes.
Both Rutherford backscatterings of He-4(+) beams and non-Rutherford backscatterings of He-4(+) and H+ beams have been used in this study to investigate the depth profiles of B dopant in Mg target upon B implantation and post annealing. Primitive data analysis suggests an enhanced diffusion of surface C contaminant during the B implantation process, together with enhanced surface oxidation upon implantation and thermal annealing in flowing N-2 atmosphere. Published by Elsevier B.V.
Films of ZnO have been implanted with fluxes of Co and Eu ions so as to give a layer of Zn0.96Co0.04O or Zn0.96Eu0.04O or Zn0.92Co0.04Eu0.04O that is approximately 15 nm thick. The ZnO films were deposited by pulsed laser deposition and had an O-polar surface. The properties of the as-implanted films were compared with those obtained after annealing in air and vacuum. The amount of radiation damage was measured using Raman scattering. Measurements of the lattice constants and EXAFS demonstrated that after annealing in air the Co2+ were on Zn sites in the lattice and Eu3+ ions were surrounded by oxygen ions. The air-annealed films were ferromagnetic and the magnetic moment of the ZnCoEuO was close to the sum of that from ZnCoO and ZnEuO. This method of producing ferromagnetic ZnCoO and ZnEuO films was competitive with other methods including pulsed laser deposition.