Josh Reding

Dr Joshua Reding

Postgraduate Research Student
+44 (0)1483 682740
05 ATI 01


My research project



Imaging Excited-State Dynamics in Two-Dimensional Semiconductors with Emerging Ultrafast Measurement Techniques

Bowei Li, Jun Deng, Joel A. Smith, Pietro Caprioglio, Kangyu Ji, Deying Luo, James D. McGettrick, K. D. G. Imalka Jayawardena, Rachel Kilbride, AOBO REN, Stephen Sweeney, Steven John Hinder, Jinxin Bi, S Ravi Pradip Silva, Wei Zhang, THOMAS WEBB, Igor Marko, Xueping Liu, YUREN XIANG, Joshua Dean Reding, HUI LI, Shixuan Du, D. G. Lidzey, Samuel D. Stranks, Trystan M. Watson, H. J. Snaith (2022)Suppressing Interfacial Recombination with a Strong-Interaction Surface Modulator for Efficient Inverted Perovskite Solar Cells, In: Advanced energy materials Wiley

Successful manipulation of halide perovskite surfaces is typically achieved via the interactions between modulators and perovskites. Herein, it is demonstrated that a strong-interaction surface modulator is beneficial to reduce interfacial recombination losses in inverted (p-i-n) perovskite solar cells (IPSCs). Two organic ammonium salts are investigated, consisting of 4-hydroxyphenethylammonium iodide and 2-thiopheneethylammonium iodide (2-TEAI). Without thermal annealing, these two modulators can recover the photoluminescence quantum yield of the neat perovskite film in contact with fullerene electron transport layer (ETL). Compared to the hydroxyl-functionalized phenethylammonium moiety, the thienylammonium facilitates the formation of a quasi-2D structure onto the perovskite. Density functional theory and quasi-Fermi level splitting calculations reveal that the 2-TEAI has a stronger interaction with the perovskite surface, contributing to more suppressed non-radiative recombination at the perovskite/ETL interface and improved open-circuit voltage (V-OC) of the fabricated IPSCs. As a result, the V-OC increases from 1.11 to 1.20 V (based on a perovskite bandgap of 1.63 eV), yielding a power conversion efficiency (PCE) from approximate to 20% to 21.9% (stabilized PCE of 21.3%, the highest reported PCEs for IPSCs employing poly[N,N ''-bis(4-butylphenyl)-N,N ''-bis(phenyl)benzidine] as the hole transport layer, alongside the enhanced operational and shelf-life stability for unencapsulated devices.